As soon as the cutscene is over and the chapter two title appears on-screen, the photo opportunity (#1) is immediately on your right where you stand.

Press triangle to snap a sneaky photo of Asav and his men below.

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(1 of 2) Photo #1 at the very start of chapter 2

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Photo #1 at the very start of chapter 2 (left), Take a look at your phone to see the photos you've just taken! (right)