Here’s the comprehensive list of requests that villagers will put forth to you in the 5-star village quest tier. As usual, they are arranged starting with Kokoto requests, then Pokke, Yukumo, and finally Bherna!
Objective: Hunt 2 Gypceros before time expires or deliver a Paw Pass Ticket
Notes: Talk to the Wycoon in Kokoto Village for this request. This is your standard run of the mill hunt-a-thon, so if you need Gypceros just keep hunting them until you’re sick and tired of it, or hunt two and deliver the Paw Pass Ticket which will be deposited in your box.
Completion of this quest will net you with the Yukumo Riceflour so you can make the Dual Blades White Dango. You’ll also unlock the 3-star Hunter Hub quest "Fossilized Memories".
Objective: Hunt 2 Khezu before time expires or deliver a Paw Pass Ticket
Location: Arctic Ridge
Notes: Talk to the Yukumo Gal in Yukumo Village for this quest. If you need more Khezu materials and you have a stomach strong enough to last, this is the quest for you.
Completion of this quest will unlock the Dianthus and Campanile armor sets. Your Palico will also get the F Yukumo Fan and F Pretty gear.
Objective: Hunt a Lagiacrus
Location: Misty Peaks
Subquest: Mount and topple monster twice
Notes: To see this request pop you, you need to complete the 4-star village quest "Royal Pains" and also have completed the 5-star key quest "The Fisherman’s Fiend". Then, chat up the Head Moga Farmer in Yukumo. You’ve already hunted one Lagiacrus before, so you can do it again! Just be sure to have armor resilient to Thunder or you’ll be in for a hard time.
Completing this quest rewards you with the Heftcorn so you can make the Gunlance Cornpopper .
Objective: Hunt a Rathalos
Location: Deserted Island
Notes: To see this request pop you, you need to complete the 2-star village quest "Arzuros the Azure Beast" and also complete the 5-star key quest "A King, Robed in Smoke". Then talk to the Tubular a.k.a stoned Tabby in Yukumo Village’s footbath.
Completion of this quest rewards you with a new Hunting Art plus a new Kitchen ingredient: Fluffy Waffle.